Photocatalytic benzylic C-H bond oxidation with a flavin scandium complex.
نویسندگان
چکیده
The enhanced reduction potential of riboflavin tetraacetate coordinating to scandium triflate enables the challenging photocatalytic C-H oxidation of electron-deficient alkylbenzenes and benzyl alcohols.
منابع مشابه
Activation and Oxidation of Mesitylene C−H Bonds by (Phebox)Iridium(III) Complexes
A pincer iridium(III) complex, (Phebox)Ir(OAc)2OH2 (1) (Phebox = 3,5-dimethylphenyl-2,6-bis(oxazolinyl)), selectively cleaves the benzylic C−H bond of mesitylene to form an isolable iridium mesityl complex, (Phebox)Ir(mesityl)(OAc) (3), in >90% yield. The trifluoroacetate analogue, (Phebox)Ir(OCOCF3)2OH2 (2), was synthesized to compare with complex 1 for C−H activation, and (Phebox)Ir(mesityl)(...
متن کاملCo(III)@Fe3O4@SiO2 salen complex as a highly selective and recoverable magnetic nanocatalyst for the oxidation of sulfides and benzylic alcohols
In this study, Co (III) salen complex was synthesized and immobilized onto the surface of Fe3O4@SiO2 magnetic nanoparticle. The heterogeneous nanocatalyst was characterized by different techniques including X-ray diffraction (XRD), Fourier transform infrared spectra (FT-IR), thermogravimetric analysis (TGA), transmission electron microscopy (TEM), nitrogen adsorption−desorption isotherm (BET), ...
متن کاملSetting Cyclohexane Stereochemistry with Oxidation
Thanks to its atomand step-economy, C–H bond oxidation represents a “hot topic” in synthetic chemistry. However, due to the ubiquity of such bonds in organic molecules, regioand enantioselective C–H bond oxidation turns out to be extremely challenging, and efficient direct methods are in high demand. Compared to the success of aliphatic sp C–H oxidation by enzymes (such as cytochrome P450, Figu...
متن کاملCatalytic Enantioselective Carbon-Oxygen Bond Formation: Phosphine-Catalyzed Synthesis of Benzylic Ethers via the Oxidation of Benzylic C-H Bonds.
Benzylic alcohols and ethers are common subunits in bioactive molecules, as well as useful intermediates in organic chemistry. In this Communication, we describe a new approach to the enantioselective synthesis of benzylic ethers through the chiral phosphine-catalyzed coupling of two readily available partners, γ-aryl-substituted alkynoates and alcohols, under mild conditions. In this process, ...
متن کاملA mononuclear non-heme manganese(IV)-oxo complex binding redox-inactive metal ions.
Redox-inactive metal ions play pivotal roles in regulating the reactivities of high-valent metal-oxo species in a variety of enzymatic and chemical reactions. A mononuclear non-heme Mn(IV)-oxo complex bearing a pentadentate N5 ligand has been synthesized and used in the synthesis of a Mn(IV)-oxo complex binding scandium ions. The Mn(IV)-oxo complexes were characterized with various spectroscopi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 51 40 شماره
صفحات -
تاریخ انتشار 2015